| 胡源,胡进良,范维澄,王清安.含羟基环三磷腈衍生物的合成及其对聚氨酯的阻燃改性[J].火灾科学,1996,5(2):12-16. |
| 含羟基环三磷腈衍生物的合成及其对聚氨酯的阻燃改性 |
| Synthesis of Cyclotriphosphazene Hydroxy-Derivatation and Flame Retarding Modification of Polyurethane |
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| DOI：10.3969/j.issn.1004-5309.年.期.顺序 |
| 基金项目:国家自然科学基金 |
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| 中文关键词: 聚氨酯 环三磷腈 氧指数（L0I） |
| 英文关键词:Polyurethane Cyclotriphosphazene Limited oxygen index(LOI) |
| 摘要点击次数: 877 |
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| 中文摘要: |
| 文从改性聚氨酯泡沫塑料（ＰＵ）着手，合成了２，４，６－三酚氧基－２，４，６－三（羟基乙氧基）环三磷腈（Ⅱ），探索了各步的分离提纯方法，鉴定了化合物的结构。实验结果表明，化合物Ⅱ可与异氰酸酯发生反应，当化合物Ⅱ加到聚氨酯泡沫塑料中时，可提高ＰＵ的阻燃性能，当含磷量为１．５－２．０％时，可得到自熄性的聚氨酯泡沫塑料。 |
| 英文摘要: |
| Triphenoxy-2、4、6-Tri(hydyoxyethoxy) cyclotriphozphazene(Ⅱ)was synthesized in view of the flame retarding modification of polyurethane.Its separation and purification has been studied arid its structure has been idenfied.It was shown that compound Ⅱcould react with isocynanate(such as TDI).When compound Ⅱwas added to polyurethane(PU),Flame retarding property of polyurethane was improved.Selfxtinguished polyurethane foams in which the content of phorphorus reached 1.5-2.0% were obtained by grafted PU with the compound Ⅱ |
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