| 张蕤,胡源,宋磊,朱玉瑞,范维澄,陈祖耀.水热法合成层状化合物α-磷酸锆[J].火灾科学,2001,10(2):123-126. |
| 水热法合成层状化合物α-磷酸锆 |
| Hydrothermal Synthesis and Characterization of the Layered Compound of α-Zirconium Hydrophosphate |
| 投稿时间：2001-03-02 |
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| DOI：10.3969/j.issn.1004-5309.年.期.顺序 |
| 基金项目: |
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| 中文关键词: 水热合成 层状化合物 热重分析 |
| 英文关键词:hydrothermal synthesis layered compounds thermogravimetric analysis |
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| 中文摘要: |
| 用水热法合成了αZr(HPO4) 2·H2O(αZrP)晶体 ,并采用XRD、IR、TEM和TG—DSC等方法对其进行了表征。结果显示 ,用该法制得的α—ZrP ,具有良好的结晶度 ,层间距达到 7.65 ,平均粒度为 900×300nm ,呈较规则的六边形薄片状 ,晶形完美 ,并具有较高的热稳定性。获得了水热法合成αZrP的优化实验条件为 :磷酸浓度5M—10M和180℃下反应48小时以上. |
| 英文摘要: |
| Crystalline samples of α zirconium hydrophosphate (abbreviated as α ZrP) were prepared by hydrothermal method and characterized by XRD, IR, TEM and TG DSC. There are highly crystalline with an interlayer distance of 7.63? and hexagonal flakes in α ZrP. Meanwhile, it is shown that α ZrP possesses a high thermal stability. The optimum experimental condition for hydrothermal method is at 180℃in 5M～10M phosphoric acid beyond 48 hours. |
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